C-Protonation of Adamantylphosphaacetylene (1-AdC≡P) and tert-Butylphosphaacetylene (tBuC≡P) in Superacids: Phosphavinyl Cation Generation and Trapping To Form Phosphaalkenes, Formation of Isomeric Boron-Containing Spirocyclic Betaines by Reaction of 1-AdC≡P with B(OTf)3, and Theoretical Studies on Protonation of MeC≡P

Kenneth K. Laali; Bernhard Geissler; Manfred Regitz; John J. Houser

doi:10.1021/jo00125a023

C-Protonation of Adamantylphosphaacetylene (1-AdC≡P) and tert-Butylphosphaacetylene (tBuC≡P) in Superacids: Phosphavinyl Cation Generation and Trapping To Form Phosphaalkenes, Formation of Isomeric Boron-Containing Spirocyclic Betaines by Reaction of 1-AdC≡P with B(OTf)₃, and Theoretical Studies on Protonation of MeC≡P

Kenneth K. Laali, Bernhard Geissler, Manfred Regitz, John J. Houser

Kent State University

Research output: Contribution to journal › Article › peer-review

Original language	English
Pages (from-to)	6362-6367
Number of pages	6
Journal	Journal of Organic Chemistry
Volume	60
Issue number	20
DOIs	https://doi.org/10.1021/jo00125a023
State	Published - Oct 1 1995
Externally published	Yes

ASJC Scopus Subject Areas

Organic Chemistry

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Laali, K. K., Geissler, B., Regitz, M., & Houser, J. J. (1995). C-Protonation of Adamantylphosphaacetylene (1-AdC≡P) and tert-Butylphosphaacetylene (tBuC≡P) in Superacids: Phosphavinyl Cation Generation and Trapping To Form Phosphaalkenes, Formation of Isomeric Boron-Containing Spirocyclic Betaines by Reaction of 1-AdC≡P with B(OTf)₃, and Theoretical Studies on Protonation of MeC≡P. Journal of Organic Chemistry, 60(20), 6362-6367. https://doi.org/10.1021/jo00125a023

C-Protonation of Adamantylphosphaacetylene (1-AdC≡P) and tert-Butylphosphaacetylene (tBuC≡P) in Superacids: Phosphavinyl Cation Generation and Trapping To Form Phosphaalkenes, Formation of Isomeric Boron-Containing Spirocyclic Betaines by Reaction of 1-AdC≡P with B(OTf)₃, and Theoretical Studies on Protonation of MeC≡P. / Laali, Kenneth K.; Geissler, Bernhard; Regitz, Manfred et al.
In: Journal of Organic Chemistry, Vol. 60, No. 20, 01.10.1995, p. 6362-6367.

Research output: Contribution to journal › Article › peer-review

Laali, KK, Geissler, B, Regitz, M & Houser, JJ 1995, 'C-Protonation of Adamantylphosphaacetylene (1-AdC≡P) and tert-Butylphosphaacetylene (tBuC≡P) in Superacids: Phosphavinyl Cation Generation and Trapping To Form Phosphaalkenes, Formation of Isomeric Boron-Containing Spirocyclic Betaines by Reaction of 1-AdC≡P with B(OTf)₃, and Theoretical Studies on Protonation of MeC≡P', Journal of Organic Chemistry, vol. 60, no. 20, pp. 6362-6367. https://doi.org/10.1021/jo00125a023

Laali KK, Geissler B, Regitz M, Houser JJ. C-Protonation of Adamantylphosphaacetylene (1-AdC≡P) and tert-Butylphosphaacetylene (tBuC≡P) in Superacids: Phosphavinyl Cation Generation and Trapping To Form Phosphaalkenes, Formation of Isomeric Boron-Containing Spirocyclic Betaines by Reaction of 1-AdC≡P with B(OTf)₃, and Theoretical Studies on Protonation of MeC≡P. Journal of Organic Chemistry. 1995 Oct 1;60(20):6362-6367. doi: 10.1021/jo00125a023

Laali, Kenneth K. ; Geissler, Bernhard ; Regitz, Manfred et al. / C-Protonation of Adamantylphosphaacetylene (1-AdC≡P) and tert-Butylphosphaacetylene (tBuC≡P) in Superacids : Phosphavinyl Cation Generation and Trapping To Form Phosphaalkenes, Formation of Isomeric Boron-Containing Spirocyclic Betaines by Reaction of 1-AdC≡P with B(OTf)₃, and Theoretical Studies on Protonation of MeC≡P. In: Journal of Organic Chemistry. 1995 ; Vol. 60, No. 20. pp. 6362-6367.

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