Electrophilic addition of propargylic cations to allenes: Formation of crowded chloro- and azido-enynes by trapping of the resulting allylic cations with TMSX (X = Cl, N3): A synthetic and computational study

Kenneth K. Laali; Ganesh C. Nandi; Gabriela L. Borosky; G. G.K.S.Narayana Kumar

doi:10.1002/ejoc.201300553

Electrophilic addition of propargylic cations to allenes: Formation of crowded chloro- and azido-enynes by trapping of the resulting allylic cations with TMSX (X = Cl, N₃): A synthetic and computational study

Kenneth K. Laali, Ganesh C. Nandi, Gabriela L. Borosky, G. G.K.S.Narayana Kumar

Chemistry and Biochemistry

University of North Florida

Research output: Contribution to journal › Article › peer-review

Original language	English
Pages (from-to)	5455-5463
Number of pages	9
Journal	European Journal of Organic Chemistry
Issue number	24
DOIs	https://doi.org/10.1002/ejoc.201300553
State	Published - Aug 2013

ASJC Scopus Subject Areas

Physical and Theoretical Chemistry
Organic Chemistry

Keywords

Alkynes
Allenes
Density functional calculations
Enynes
Reaction mechanisms

Access to Document

10.1002/ejoc.201300553

Cite this

Laali, K. K., Nandi, G. C., Borosky, G. L., & Kumar, G. G. K. S. N. (2013). Electrophilic addition of propargylic cations to allenes: Formation of crowded chloro- and azido-enynes by trapping of the resulting allylic cations with TMSX (X = Cl, N₃): A synthetic and computational study. European Journal of Organic Chemistry, (24), 5455-5463. https://doi.org/10.1002/ejoc.201300553

Electrophilic addition of propargylic cations to allenes: Formation of crowded chloro- and azido-enynes by trapping of the resulting allylic cations with TMSX (X = Cl, N₃): A synthetic and computational study. / Laali, Kenneth K.; Nandi, Ganesh C.; Borosky, Gabriela L. et al.
In: European Journal of Organic Chemistry, No. 24, 08.2013, p. 5455-5463.

Research output: Contribution to journal › Article › peer-review

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