N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF3)=NTf] and N-aryltriflimides Ar-N(Tf)2 by thermal and photolytic dediazoniation of [ArN2][BF4] in [BMIM][Tf2N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion

Kenneth K. Laali; Takao Okazaki; Scott D. Bunge

doi:10.1021/jo0708801

N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion

Kenneth K. Laali, Takao Okazaki, Scott D. Bunge

Kent State University

Research output: Contribution to journal › Article › peer-review

Original language	English
Pages (from-to)	6758-6762
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	72
Issue number	18
DOIs	https://doi.org/10.1021/jo0708801
State	Published - Aug 31 2007
Externally published	Yes

ASJC Scopus Subject Areas

Organic Chemistry

Access to Document

10.1021/jo0708801

Cite this

Laali, K. K., Okazaki, T., & Bunge, S. D. (2007). N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion. Journal of Organic Chemistry, 72(18), 6758-6762. https://doi.org/10.1021/jo0708801

N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion. / Laali, Kenneth K.; Okazaki, Takao; Bunge, Scott D.
In: Journal of Organic Chemistry, Vol. 72, No. 18, 31.08.2007, p. 6758-6762.

Research output: Contribution to journal › Article › peer-review

Laali, KK, Okazaki, T & Bunge, SD 2007, 'N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion', Journal of Organic Chemistry, vol. 72, no. 18, pp. 6758-6762. https://doi.org/10.1021/jo0708801

Laali KK, Okazaki T, Bunge SD. N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion. Journal of Organic Chemistry. 2007 Aug 31;72(18):6758-6762. doi: 10.1021/jo0708801

Laali, Kenneth K. ; Okazaki, Takao ; Bunge, Scott D. / N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid : Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion. In: Journal of Organic Chemistry. 2007 ; Vol. 72, No. 18. pp. 6758-6762.

@article{c36fbd73c5f744979f96ab03a0c3956d,

title = "N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF3)=NTf] and N-aryltriflimides Ar-N(Tf)2 by thermal and photolytic dediazoniation of [ArN2][BF4] in [BMIM][Tf2N] ionic liquid: Exploiting the ambident nucleophilic character of a {"}nonnucleophilic{"} anion",

author = "Laali, \{Kenneth K.\} and Takao Okazaki and Bunge, \{Scott D.\}",

year = "2007",

month = aug,

day = "31",

doi = "10.1021/jo0708801",

language = "English",

volume = "72",

pages = "6758--6762",

number = "18",

}

TY - JOUR

T1 - N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF3)=NTf] and N-aryltriflimides Ar-N(Tf)2 by thermal and photolytic dediazoniation of [ArN2][BF4] in [BMIM][Tf2N] ionic liquid

T2 - Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion

AU - Laali, Kenneth K.

AU - Okazaki, Takao

AU - Bunge, Scott D.

PY - 2007/8/31

Y1 - 2007/8/31

UR - https://www.scopus.com/pages/publications/34548789522

UR - https://www.scopus.com/inward/citedby.url?scp=34548789522&partnerID=8YFLogxK

U2 - 10.1021/jo0708801

DO - 10.1021/jo0708801

M3 - Article

AN - SCOPUS:34548789522

SN - 0022-3263

VL - 72

SP - 6758

EP - 6762

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 18

ER -

N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF3)=NTf] and N-aryltriflimides Ar-N(Tf)2 by thermal and photolytic dediazoniation of [ArN2][BF4] in [BMIM][Tf2N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion

ASJC Scopus Subject Areas

Access to Document

Other files and links

Cite this

N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion