N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF3)=NTf] and N-aryltriflimides Ar-N(Tf)2 by thermal and photolytic dediazoniation of [ArN2][BF4] in [BMIM][Tf2N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion

Kenneth K. Laali; Takao Okazaki; Scott D. Bunge

doi:10.1021/jo0708801

N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion

Kenneth K. Laali
, Takao Okazaki
, Scott D. Bunge

Kent State University

Research output: Contribution to journal › Article › peer-review

Original language	English
Pages (from-to)	6758-6762
Number of pages	5
Journal	Journal of Organic Chemistry
Volume	72
Issue number	18
DOIs	https://doi.org/10.1021/jo0708801
State	Published - Aug 31 2007
Externally published	Yes

ASJC Scopus Subject Areas

Organic Chemistry

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10.1021/jo0708801

Cite this

Laali, K. K., Okazaki, T., & Bunge, S. D. (2007). N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion. Journal of Organic Chemistry, 72(18), 6758-6762. https://doi.org/10.1021/jo0708801

N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion. / Laali, Kenneth K.; Okazaki, Takao; Bunge, Scott D.
In: Journal of Organic Chemistry, Vol. 72, No. 18, 31.08.2007, p. 6758-6762.

Research output: Contribution to journal › Article › peer-review

Laali, KK, Okazaki, T & Bunge, SD 2007, 'N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion', Journal of Organic Chemistry, vol. 72, no. 18, pp. 6758-6762. https://doi.org/10.1021/jo0708801

Laali KK, Okazaki T, Bunge SD. N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion. Journal of Organic Chemistry. 2007 Aug 31;72(18):6758-6762. doi: 10.1021/jo0708801

Laali, Kenneth K. ; Okazaki, Takao ; Bunge, Scott D. / N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid : Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion. In: Journal of Organic Chemistry. 2007 ; Vol. 72, No. 18. pp. 6758-6762.

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N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF3)=NTf] and N-aryltriflimides Ar-N(Tf)2 by thermal and photolytic dediazoniation of [ArN2][BF4] in [BMIM][Tf2N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion

ASJC Scopus Subject Areas

Access to Document

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Cite this

N-(trifluoromethylsulfonyl)aryloxytrifluoromethylsulfoximines [ArO-SO(CF₃)=NTf] and N-aryltriflimides Ar-N(Tf)₂ by thermal and photolytic dediazoniation of [ArN₂][BF₄] in [BMIM][Tf₂N] ionic liquid: Exploiting the ambident nucleophilic character of a "nonnucleophilic" anion